News and Notices
  28 April 2017: Denmark Embassy in Bolivia will not accept more short term visa applications from 30 April 2017 onwards due to closure. For this reason the Visa application centres in Ecuador also won’t be able to receive short term visa applications until further notice.

The Embassy of Denmark in La Paz (Bolivia) reports that as of 13 February 2017, it is no longer in charge of long-stay / residency visa applications. However VFS Global continues to receive visa applications.
The Embassy of Denmark in Bogotá (Colombia) will be in charge of processing applications for Residence Permits to Denmark (stay longer than 90 days).
For general information about Schengen visas and Residence Permits to Denmark you can access the link, Migrations from Denmark:

Applicants for Schengen Visas (stay up to 90 days) from Denmark to Denmark may continue submitting their application to VFS Global in Quito and Guayaquil, for the moment and until further notice, Schengen visa applications (stay up to 90 days) will continue Being processed by the Embassy of Denmark in La Paz (Bolivia).